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Atomically precise Au(144)(SR)(60) nanoclusters (R = Et, Pr) are capped by 12 distinct ligand types of 5-fold equivalence and display gigantic diastereotopic effects
For two decades, Au(144)(SR)(60) has been one of the most studied and used thiolate (SR) protected gold nanoclusters. In many ways, however, it proved to be a challenging and elusive case, also because of the difficulties in solving its structure by single-crystal X-ray crystallography. We used very...
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| Publié dans: | Chem Sci |
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| Auteurs principaux: | , , , , , , , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
Royal Society of Chemistry
2018
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6301266/ https://ncbi.nlm.nih.gov/pubmed/30647884 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc04092c |
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