Atomically precise Au(144)(SR)(60) nanoclusters (R = Et, Pr) are capped by 12 distinct ligand types of 5-fold equivalence and display gigantic diastereotopic effects

For two decades, Au(144)(SR)(60) has been one of the most studied and used thiolate (SR) protected gold nanoclusters. In many ways, however, it proved to be a challenging and elusive case, also because of the difficulties in solving its structure by single-crystal X-ray crystallography. We used very...

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Опубликовано в: :Chem Sci
Главные авторы: Dainese, Tiziano, Agrachev, Mikhail, Antonello, Sabrina, Badocco, Denis, Black, David M., Fortunelli, Alessandro, Gascón, José A., Stener, Mauro, Venzo, Alfonso, Whetten, Robert L., Maran, Flavio
Формат: Artigo
Язык:Inglês
Опубликовано: Royal Society of Chemistry 2018
Предметы:
Chemistry
Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC6301266/
https://ncbi.nlm.nih.gov/pubmed/30647884
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc04092c
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