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Hydrolytic decomposition of S-aroylthiooximes: Effect of pH and N-arylidene substitution on reaction rate

The hydrolytic decomposition of four peptides containing S-aroylthiooximes (SATOs) with variable N-arylidene substituents was investigated in 10 aqueous buffer solutions at pH values ranging from 6.0 to 10.9. UV-Vis spectroscopy was employed to study the reaction kinetics, which revealed V-shaped pH...

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Bibliografische gegevens
Gepubliceerd in:J Org Chem
Hoofdauteurs: Kaur, Kuljeet, Qian, Yun, Gandour, Richard D., Matson, John B.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2018
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Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6294146/
https://ncbi.nlm.nih.gov/pubmed/30347157
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.8b02151
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