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Controlling Pd(IV) reductive-elimination pathways enables Pd(II)-catalyzed enantioselective C(sp(3))–H fluorination
The development of a Pd(II)-catalyzed enantioselective fluorination of C(sp(3))–H bonds would offer a new approach to making chiral organofluorines. However, such a strategy is particularly challenging because of the difficulty in differentiating prochiral C(sp(3))–H bonds through Pd(II)-insertion,...
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| Опубликовано в: : | Nat Chem |
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| Главные авторы: | , , , |
| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
2018
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6289870/ https://ncbi.nlm.nih.gov/pubmed/29892027 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41557-018-0048-1 |
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