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Switching Chemoselectivity: Using Mechanochemistry to Alter Reaction Kinetics

A reaction manifold has been discovered in which the chemoselectivity can be altered by switching between neat milling and liquid assisted grinding (LAG) with polar additives. After investigation of the reaction mechanism, it has been established that this switching in reaction pathway is due to the...

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Bibliografiske detaljer
Udgivet i:Angew Chem Int Ed Engl
Main Authors: Howard, Joseph L., Brand, Michael C., Browne, Duncan L.
Format: Artigo
Sprog:Inglês
Udgivet: John Wiley and Sons Inc. 2018
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6282732/
https://ncbi.nlm.nih.gov/pubmed/30335216
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201810141
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