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Auto-Tandem Catalysis in Ionic Liquids: Synthesis of 2-Oxazolidinones by Palladium-Catalyzed Oxidative Carbonylation of Propargylic Amines in EmimEtSO(4)

A convenient carbonylative approach to 2-oxazolidinone derivatives carried out using an ionic liquid (1-ethyl-3-methylimidazolium ethyl sulfate, EmimEtSO(4)) as the solvent is presented. It is based on the sequential concatenation of two catalytic cycles, both catalyzed by the same metal species (au...

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Detalhes bibliográficos
Publicado no:Molecules
Main Authors: Mancuso, Raffaella, Maner, Asif, Ziccarelli, Ida, Pomelli, Christian, Chiappe, Cinzia, Della Ca’, Nicola, Veltri, Lucia, Gabriele, Bartolo
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6273147/
https://ncbi.nlm.nih.gov/pubmed/27399662
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules21070897
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