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Tandem semi-hydrogenation/isomerization of propargyl alcohols to saturated carbonyl analogues by dodecanethiolate-capped palladium nanoparticle catalysts

The efficient one-pot conversion of propargyl alcohols to their saturated carbonyl analogues is carried out for the first time using metal nanoparticle catalysts, dodecanethiolate-capped Pd nanoparticles. Kinetic studies reveal that the reaction progresses through a semi-hydrogenation intermediate (...

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Detalhes bibliográficos
Publicado no:RSC Adv
Main Authors: Gavia, Diego J., Koeppen, Jordan, Sadeghmoghaddam, Elham, Shon, Young-Seok
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5025254/
https://ncbi.nlm.nih.gov/pubmed/27642511
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c3ra42119h
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