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Gas Phase Thermal Reactions of exo-8-Cyclopropyl-bicyclo[4.2.0]oct-2-ene (1-exo)

The title compound 1-exo (with minor amounts of its C8 epimer 1-endo) was prepared by Wolff-Kishner reduction of the cycloadduct of 1,3-cyclohexadiene and cyclopropylketene. The [1,3]-migration product 2-endo was synthesized by efficient selective cyclopropanation of endo-5-vinylbicyclo[2.2.2]oct-2-...

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Detalhes bibliográficos
Publicado no:Molecules
Main Authors: Leber, Phyllis A., Nocket, Anthony J., Hancock-Cerutti, William, Bemis, Christopher Y., Khine, Wint Khant, Mohrbacher III, Joseph A., Baldwin, John E.
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2014
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6271342/
https://ncbi.nlm.nih.gov/pubmed/24473211
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules19021527
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