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Pauson-Khand Reaction of Internal Dissymmetric Trifluoromethyl Alkynes. Influence of the Alkene on the Regioselectivity

The scope of the Pauson-Khand reaction (PKR) of internal trifluoromethyl alkynes, previously described with norbornadiene, is expanded to norbornene and ethylene. A thorough structural analysis of the resulting PK adducts has been carried out to unveil that α-trifluoromethylcyclopentenones are prefe...

Deskribapen osoa

Gorde:
Xehetasun bibliografikoak
Argitaratua izan da:Molecules
Egile Nagusiak: Aiguabella, Nuria, Arce, Elsa M., del Pozo, Carlos, Verdaguer, Xavier, Riera, Antoni
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: MDPI 2014
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC6271263/
https://ncbi.nlm.nih.gov/pubmed/24496269
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules19021763
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