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Co-complexes Derived from Alkene Insertion to Alkyne-dicobaltpentacarbonyl complexes: Insight into the Regioselectivity of Pauson-Khand Reactions of Cyclopropenes

[Image: see text] Described are the X-ray crystallographic and spectral properties of Co-complexes that were isolated from two Pauson-Khand reactions of chiral cyclopropenes. These are the first examples of isolated Co-complexes derived from the putative alkene-insertion intermediates of Pauson-Khan...

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Detalhes bibliográficos
Main Authors: Pallerla, Mahesh K., Yap, Glenn P. A., Fox, Joseph M.
Formato: Artigo
Idioma:Inglês
Publicado em: 2008
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2667904/
https://ncbi.nlm.nih.gov/pubmed/18637694
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo800776z
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