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NMR Structural Study of the Prototropic Equilibrium in Solution of Schiff Bases as Model Compounds

An NMR titration method has been used to simultaneously measure the acid dissociation constant (pK(a)) and the intramolecular NHO prototropic constant ΔK(NHO) on a set of Schiff bases. The model compounds were synthesized from benzylamine and substituted ortho-hydroxyaldehydes, appropriately substit...

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Vydáno v:Molecules
Hlavní autoři: Ortegón-Reyna, David, Garcías-Morales, Cesar, Padilla-Martínez, Itzia, García-Báez, Efren, Aríza-Castolo, Armando, Peraza-Campos, Ana, Martínez-Martínez, Francisco
Médium: Artigo
Jazyk:Inglês
Vydáno: MDPI 2013
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6271073/
https://ncbi.nlm.nih.gov/pubmed/24384925
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules19010459
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