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Palladium(II)-Catalyzed othro-C–H-Benzoxylation of 2-Arylpyridines by Oxidative Coupling with Aryl Acylperoxides

A palladium(II)-catalyzed ortho-benzoxylation of 2-arylpyridines with aryl acylperoxides was developed. With pyridyl as directing group, the benzoxylation reaction exhibits remarkable regioselectivity and excellent functional group tolerance, providing the products in up to 87% yield.

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Detalhes bibliográficos
Publicado no:Molecules
Main Authors: Sit, Wing-Nga, Chan, Chun-Wo, Yu, Wing-Yiu
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6270440/
https://ncbi.nlm.nih.gov/pubmed/23591922
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules18044403
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