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The Rotational Barrier in Ethane: A Molecular Orbital Study

The energy change on each Occupied Molecular Orbital as a function of rotation about the C-C bond in ethane was studied using the B3LYP, mPWB95 functional and MP2 methods with different basis sets. Also, the effect of the ZPE on rotational barrier was analyzed. We have found that σ and π energies co...

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Bibliografiset tiedot
Julkaisussa:Molecules
Päätekijät: Quijano-Quiñones, Ramiro F., Quesadas-Rojas, Mariana, Cuevas, Gabriel, Mena-Rejón, Gonzalo J.
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: MDPI 2012
Aiheet:
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC6268250/
https://ncbi.nlm.nih.gov/pubmed/22522396
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules17044661
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