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The Energy of Substituted Ethanes. Asymmetry Orbitals
The leading terms in the energy of a general substituted ethane are derived in explicit form as a function of the torsional angle θ, the substituent electronegativities, and their mutual overlaps. The energy is found to be the sum of all four overlaps between pairs of asymmetry orbitals, and satisfi...
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| Publicado no: | Proc Natl Acad Sci U S A |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
1973
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC433298/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16592060/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.70.2.531 |
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