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Rhodium-Catalyzed Linear Codimerization and Cycloaddition of Ketenes with Alkynes

A novel rhodium-catalyzed linear codimerization of alkyl phenyl ketenes with internal alkynes to dienones and a novel synthesis of furans by an unusual cycloaddition of diaryl ketenes with internal alkynes have been developed. These reactions proceed smoothly with the same rhodium catalyst, RhCl(PPh...

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Detalhes bibliográficos
Publicado no:Molecules
Main Authors: Kondo, Teruyuki, Niimi, Masatsugu, Yoshida, Yuki, Wada, Kenji, Mitsudo, Take-aki, Kimura, Yu, Toshimitsu, Akio
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2010
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6264695/
https://ncbi.nlm.nih.gov/pubmed/20657433
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules15064189
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