Al(OCArF3)(3) – a thermally stable Lewis superacid

The adduct free Lewis superacid Al(OCArF3)(3) was obtained by the reaction of ArF3COH with AlEt(3) and fully characterized (Ar(F) = C(6)F(5)). It comprises a high thermal stability up to 180 °C and a distinct reactivity towards Lewis bases, as exemplified by the isolation of the neutral adducts Al(O...

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Bibliografiske detaljer
Udgivet i:Chem Sci
Main Authors: Kögel, Julius F., Timoshkin, Alexey Y., Schröder, Artem, Lork, Enno, Beckmann, Jens
Format: Artigo
Sprog:Inglês
Udgivet: Royal Society of Chemistry 2018
Fag:
Chemistry
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6256356/
https://ncbi.nlm.nih.gov/pubmed/30568768
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc02981d
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