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A Novel Synthetic Approach to C-Glycosyl-d- and l-Alanines
C-Glycosyl-(S)- and (R)-alanines 12a and 12b were synthesized from the known β-C-glycoside 1. The nitrogen function was introduced by aza-Claisen rearrangement of the allylic thiocyanate 7, derived from the corresponding alcohol 6. The absolute configuration of the newly created chiral carbon center...
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| Gepubliceerd in: | Molecules |
|---|---|
| Hoofdauteurs: | , , , , , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
MDPI
2008
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6244940/ https://ncbi.nlm.nih.gov/pubmed/19078857 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules13123171 |
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