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A Novel Synthetic Approach to C-Glycosyl-d- and l-Alanines

C-Glycosyl-(S)- and (R)-alanines 12a and 12b were synthesized from the known β-C-glycoside 1. The nitrogen function was introduced by aza-Claisen rearrangement of the allylic thiocyanate 7, derived from the corresponding alcohol 6. The absolute configuration of the newly created chiral carbon center...

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Dettagli Bibliografici
Pubblicato in:Molecules
Autori principali: Martinková, Miroslava, Gonda, Jozef, Raschmanová, Jana, Novodomská, Alexandra, Kožíšek, Jozef, Perasinová, Lucia
Natura: Artigo
Lingua:Inglês
Pubblicazione: MDPI 2008
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6244940/
https://ncbi.nlm.nih.gov/pubmed/19078857
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules13123171
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