A bench stable formal Cu(iii) N-heterocyclic carbene accessible from simple copper(ii) acetate

For years, Cu(iii)NHCs have been proposed as active intermediates in Cu(i)NHC catalyzed reactions, yielding the desired products by reductive elimination, but until today, no one has ever reported the characterisation of such a compound. When working on the synthesis of biomimetic transition metal (...

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Bibliografiske detaljer
Udgivet i:Chem Sci
Main Authors: Ghavami, Zohreh S., Anneser, Markus R., Kaiser, Felix, Altmann, Philipp J., Hofmann, Benjamin J., Schlagintweit, Jonas F., Grivani, Gholamhossein, Kühn, Fritz E.
Format: Artigo
Sprog:Inglês
Udgivet: Royal Society of Chemistry 2018
Fag:
Chemistry
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6240905/
https://ncbi.nlm.nih.gov/pubmed/30542579
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc01834k
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