A Chiral Bipyrimidine-Bridged Dy(2) SMM: A Comparative Experimental and Theoretical Study of the Correlation Between the Distortion of the DyO6N2 Coordination Sphere and the Anisotropy Barrier

Chiral bipyrimidine-bridged dinuclear Ln(III) complexes of general formula [(μ-bipym){((+)-tfacam)(3)Ln}(2)] and [(μ-bipym){((-)-tfacam)(3)Ln}(2)], have been prepared from the assembly of Ln(AcO)(3)·nH(2)O (Ln(III) = Dy, Gd), (+)/(−)-3-(trifluoroacetyl)camphor enantiopure ligands ((+)/(-)-Htfacam) a...

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Vydáno v:Front Chem
Hlavní autoři: Díaz-Ortega, Ismael F., Herrera, Juan Manuel, Reyes Carmona, Álvaro, Galán-Mascarós, José Ramón, Dey, Sourav, Nojiri, Hiroyuki, Rajaraman, Gopalan, Colacio, Enrique
Médium: Artigo
Jazyk:Inglês
Vydáno: Frontiers Media S.A. 2018
Témata:
Chemistry
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6236069/
https://ncbi.nlm.nih.gov/pubmed/30467538
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3389/fchem.2018.00537
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