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An air-stable Dy(iii) single-ion magnet with high anisotropy barrier and blocking temperature

Herein we report air-stable Dy(iii) and Er(iii) single-ion magnets (SIMs) with pseudo-D(5h) symmetry, synthesized from a sterically encumbered phosphonamide, (t)BuPO(NH(i)Pr)(2), where the Dy(iii)-SIM exhibits a magnetization blocking (T(B)) up to 12 K, defined from the maxima of the zero-field cool...

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Publicat a:Chem Sci
Autors principals: Gupta, Sandeep K., Rajeshkumar, Thayalan, Rajaraman, Gopalan, Murugavel, Ramaswamy
Format: Artigo
Idioma:Inglês
Publicat: Royal Society of Chemistry 2016
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6020529/
https://ncbi.nlm.nih.gov/pubmed/30155168
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc00279j
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