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A stereoselective synthesis of (+)-boronolide

A stereoselective synthesis of (+)-boronolide is described. The key steps involve a stereoselective reduction of an α-hydroxy ketone, allylation of an α-hydroxy aldehyde and a ring-closing olefin metathesis of a homoallylic alcohol derived acrylate ester utilizing Grubbs’ catalyst.

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Bibliografiske detaljer
Udgivet i:Tetrahedron Lett
Main Authors: Ghosh, Arun K., Bilcer, Geoffrey
Format: Artigo
Sprog:Inglês
Udgivet: 2000
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6234978/
https://ncbi.nlm.nih.gov/pubmed/30449906
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/S0040-4039(99)02246-7
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