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A stereoselective synthesis of (+)-boronolide
A stereoselective synthesis of (+)-boronolide is described. The key steps involve a stereoselective reduction of an α-hydroxy ketone, allylation of an α-hydroxy aldehyde and a ring-closing olefin metathesis of a homoallylic alcohol derived acrylate ester utilizing Grubbs’ catalyst.
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| Publicado no: | Tetrahedron Lett |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2000
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6234978/ https://ncbi.nlm.nih.gov/pubmed/30449906 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/S0040-4039(99)02246-7 |
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