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TiCl(4) Promoted Three Component Coupling Reaction : A New Method for the Synthesis of Functionalized Tetrahydrofurans and Tetrahydropyrans

TiC1(4) promoted coupling of ethyl glyoxylate and dihydrofuran or dihydropyran provided oxonium ion intermediates which upon reaction with a nucleophilic trapping agent such as allyltrimethylsilane provided 2,3-disubstituted tetrahydrofurans and pyrans in good yields. The overall protocol constitute...

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Publicat a:Tetrahedron Lett
Autors principals: Ghosh, Arun K., Kawahama, Reiko
Format: Artigo
Idioma:Inglês
Publicat: 1999
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6226096/
https://ncbi.nlm.nih.gov/pubmed/30422132
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/S0040-4039(98)02633-1
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