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HIGHLY STEREOSELECTIVE REDUCTION OF α-KETO ESTERS: UTILITY OF CIS-1-ARYLSULFONAMIDO-2-INDANOLS AS CHIRAL AUXILIARIES
The reduction of α-keto esters bearing cis-1-arylsulfonamido-2-indanol derivatives proceeded with high diastereoselectivities providing the corresponding α-hydroxy esters in excellent yields. The chiral auxiliary group is removed under mild basic conditions and recovered.
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| Publié dans: | Tetrahedron Lett |
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| Auteurs principaux: | , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2000
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6214205/ https://ncbi.nlm.nih.gov/pubmed/30393406 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/0040-4039(95)01385-U |
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