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Transition metal-free oxidative and deoxygenative C–H/C–Li cross-couplings of 2H-imidazole 1-oxides with carboranyl lithium as an efficient synthetic approach to azaheterocyclic carboranes

The direct C–H functionalization methodology has first been applied to perform transition metal-free C–H/C–Li cross-couplings of 2H-imidazole 1-oxides with carboranyllithium. This atom- and step-economical approach, based on one-pot reactions of nucleophilic substitution of hydrogen (S(N)(H)) in non...

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Detalhes bibliográficos
Publicado no:Beilstein J Org Chem
Main Authors: Smyshliaeva, Lidia A, Varaksin, Mikhail V, Slepukhin, Pavel A, Chupakhin, Oleg N, Charushin, Valery N
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6204773/
https://ncbi.nlm.nih.gov/pubmed/30410624
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.14.240
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