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Diastereoselective C–H carbonylative annulation of aliphatic amines: a rapid route to functionalized γ-lactams
A palladium(ii)-catalysed C(sp(3))–H carbonylation of free(NH) secondary aliphatic amines to 2-pyrrolidinones is described. A correlation between the nature of the carboxylate ligand and the diastereoselectivity and yield of the process was observed. As such, under these optimal conditions a range o...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6182607/ https://ncbi.nlm.nih.gov/pubmed/30393523 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc02855a |
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