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Design and synthesis of a 4-aminoquinoline-based molecular tweezer that recognizes protoporphyrin IX and iron(iii) protoporphyrin IX and its application as a supramolecular photosensitizer

We report on the design and synthesis of a new type of 4-aminoquinoline-based molecular tweezer 1 which forms a stable host–guest complex with protoporphyrin IX (PPIX) via multiple interactions in a DMSO and HEPES buffer (pH 7.4) mixed solvent system. The binding constant for the 1 : 1 complex (K(11...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Hisamatsu, Yosuke, Umezawa, Naoki, Yagi, Hirokazu, Kato, Koichi, Higuchi, Tsunehiko
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6180317/
https://ncbi.nlm.nih.gov/pubmed/30319746
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc02133c
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