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Synthesis of aryl sulfides via radical–radical cross coupling of electron-rich arenes using visible light photoredox catalysis
Electron-rich arenes react with aryl and alkyl disulfides in the presence of catalytic amounts of [Ir(dF(CF(3))ppy)(2)(dtbpy)]PF(6) and (NH(4))(2)S(2)O(8) under blue light irradiation to yield arylthiols. The reaction proceeds at room temperature and avoids the use of prefunctionalized arenes. Exper...
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| Publicado no: | Beilstein J Org Chem |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Beilstein-Institut
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6176842/ https://ncbi.nlm.nih.gov/pubmed/30344775 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.14.228 |
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