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Total Synthesis of Chaetoglobin A via Catalytic, Atroposelective Oxidative Phenol Coupling
The first total synthesis of chaetoglobin A (1), which features a chiral axis between two identical highly oxygenated bicyclic cores, was successfully completed in 12 steps from 2,6-dimethoxytoluene. Vanadium-catalyzed oxidative phenol coupling, as a key step, enabled generation of the axial chirali...
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| Publicat a: | Org Lett |
|---|---|
| Autors principals: | , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2018
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6174078/ https://ncbi.nlm.nih.gov/pubmed/30207731 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.8b02183 |
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