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Total Synthesis of Pyrolaside B: Phenol Trimerization via Sequenced Oxidative C-C and C-O Coupling
A facile method to oxidatively trimerize phenols using a low loading catalytic aerobic copper system is described. The mechanism of this transformation is probed, an understanding of which enabled cross coupling trimerizations. With this method, the natural product pyrolaside B has been synthesized...
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| Udgivet i: | Angew Chem Int Ed Engl |
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| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2020
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7200290/ https://ncbi.nlm.nih.gov/pubmed/32026544 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201915654 |
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