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Conformational Twisting of a Formate-Bridged Diiridium Complex Enables Catalytic Formic Acid Dehydrogenation
We previously reported that iridium complex 1a enables the first homogeneous catalytic dehydrogenation of neat formic acid and enjoys unusual stability through millions of turnovers. Binuclear iridium hydride species 5a, which features a provocative C2-symmetric geometry, was isolated from the react...
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| Publié dans: | Dalton Trans |
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| Auteurs principaux: | , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2018
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6168401/ https://ncbi.nlm.nih.gov/pubmed/30206593 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8dt03268h |
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