Llwytho...

Conformational Twisting of a Formate-Bridged Diiridium Complex Enables Catalytic Formic Acid Dehydrogenation

We previously reported that iridium complex 1a enables the first homogeneous catalytic dehydrogenation of neat formic acid and enjoys unusual stability through millions of turnovers. Binuclear iridium hydride species 5a, which features a provocative C2-symmetric geometry, was isolated from the react...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:Dalton Trans
Prif Awduron: Lauridsen, Paul J., Lu, Zhiyao, Celaje, Jeff J. A., Kedzie, Elyse A., Williams, Travis J.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 2018
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC6168401/
https://ncbi.nlm.nih.gov/pubmed/30206593
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8dt03268h
Tagiau: Ychwanegu Tag
Dim Tagiau, Byddwch y cyntaf i dagio'r cofnod hwn!