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Iridium Catalysts for Acceptorless Dehydrogenation of Alcohols to Carboxylic Acids: Scope and Mechanism
We introduce iridium-based conditions for the conversion of primary alcohols to potassium carboxylates (or carboxylic acids) in the presence of potassium hydroxide and either [Ir(2-PyCH(2)(C(4)H(5)N(2)))(COD)]OTf (1) or [Ir(2-PyCH(2)PBu(2)(t))(COD)]OTf (2). The method provides both aliphatic and ben...
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| Veröffentlicht in: | ACS Catal |
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| Hauptverfasser: | , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2018
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6166666/ https://ncbi.nlm.nih.gov/pubmed/30288338 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.8b00105 |
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