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Iridium Catalysts for Acceptorless Dehydrogenation of Alcohols to Carboxylic Acids: Scope and Mechanism

We introduce iridium-based conditions for the conversion of primary alcohols to potassium carboxylates (or carboxylic acids) in the presence of potassium hydroxide and either [Ir(2-PyCH(2)(C(4)H(5)N(2)))(COD)]OTf (1) or [Ir(2-PyCH(2)PBu(2)(t))(COD)]OTf (2). The method provides both aliphatic and ben...

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Bibliografski detalji
Izdano u:ACS Catal
Glavni autori: Cherepakhin, Valeriy, Williams, Travis J.
Format: Artigo
Jezik:Inglês
Izdano: 2018
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6166666/
https://ncbi.nlm.nih.gov/pubmed/30288338
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.8b00105
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