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Enantioselective Michael Addition of Cyclic β-Diones to α,β-Unsaturated Enones Catalyzed by Quinine-Based Organocatalysts

An enantioselective (52–98% ee) Michael addition between cyclic β-diones and α,β-unsaturated enones was established in the presence of quinine-based primary amine or squaramide. A variety of cinnamones were smoothly converted into the desired 3,4-dihydropyrans in moderate to high yields (63–99%). Ch...

תיאור מלא

שמור ב:
מידע ביבליוגרפי
הוצא לאור ב:Molecules
Main Authors: Wang, Qingqing, Wang, Wei, Ye, Ling, Yang, Xuejun, Li, Xinying, Zhao, Zhigang, Li, Xuefeng
פורמט: Artigo
שפה:Inglês
יצא לאור: MDPI 2017
נושאים:
גישה מקוונת:https://ncbi.nlm.nih.gov/pmc/articles/PMC6152274/
https://ncbi.nlm.nih.gov/pubmed/28665357
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules22071096
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