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Synthesis of α,β-Unsaturated Ketones as Chalcone Analogues via a S(RN)1 Mechanism

An electron-transfer chain reaction between 2-nitropropane anion and α-bromoketones derived from nitrobenzene and nitrothiophene was demonstrated by mechanistic study and a specific convenient synthetic protocol. Thus, 2-bromo-1-(5-nitrothiophen-2-yl)ethanone or 2-bromo-1-(4-nitrophenyl)ethanone wer...

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Bibliografiska uppgifter
I publikationen:Molecules
Huvudupphovsmän: Curti, Christophe, Gellis, Armand, Vanelle, Patrice
Materialtyp: Artigo
Språk:Inglês
Publicerad: MDPI 2007
Ämnen:
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC6149340/
https://ncbi.nlm.nih.gov/pubmed/17851431
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/12040797
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