Aqueous Barbier Allylation of Aldehydes Mediated by Tin

The aqueous tin-mediated Barbier reaction affords good to excellent yields and moderate syn diastereoselectivity under basic and acidic conditions. The high yields and stereoselectivity observed in the case of o-substituted aldehydes suggest a cyclic organotin intermediate or transition state in K(2...

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Bibliografiske detaljer
Udgivet i:Molecules
Main Authors: Guimarães, Ricardo L., Lima, Dimas J. P., Barros, Maria Ester S. B., Cavalcanti, Lívia N., Hallwass, Fernando, Navarro, Marcelo, Bieber, Lothar W., Malvestiti, Ivani
Format: Artigo
Sprog:Inglês
Udgivet: MDPI 2007
Fag:
Full Paper
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6149083/
https://ncbi.nlm.nih.gov/pubmed/17962728
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/12092089
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