Catalytic Properties of the Dioxomolybdenum Siloxide MoO(2)(OSiPh(3))(2) and its 2,2'-Bipyridine Adduct MoO(2)(OSiPh(3))(2)(bpy)

The tetrahedral triphenylsiloxy complex MoO(2)(OSiPh(3))(2) (1) and its Lewis base adduct with 2,2'-bipyridine, MoO(2)(OSiPh(3))(2)(bpy) (2), were prepared and characterised by IR/Raman spectroscopy, and thermogravimetric analysis. Both compounds catalyse the epoxidation of cis-cyclooctene at 5...

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Publicat a:Molecules
Autors principals: Bruno, Sofia M., Monteiro, Bernardo, Balula, Maria Salete, Lourenço, Catarina, Valente, Anabela A., Pillinger, Martyn, Ribeiro-Claro, Paulo, Gonçalves, Isabel S.
Format: Artigo
Idioma:Inglês
Publicat: MDPI 2006
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Article
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6148482/
https://ncbi.nlm.nih.gov/pubmed/17962761
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/11040298
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