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Synthesis of Cyclophellitol Utilizing a Palladium Chloride Mediated-Ferrier-II Rearrangement

Cyclophellitol and its C3-epimer have been synthesized from 5-enoglucopyranoside and 5-enomannopyranoside, respectively. The carbocyclic skeleton was constructed through a Ferrier-II reaction meditated by PdCl(2).

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Detalhes bibliográficos
Publicado no:Molecules
Main Authors: Takahashi, Hideyo, Ikegami, Shiro
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2005
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6147719/
https://ncbi.nlm.nih.gov/pubmed/18007359
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/10080901
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