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Bi(OTf)(3) and SiO(2)-Bi(OTf)(3) as Effective Catalysts for the Ferrier Rearrangement#
Bi(OTf)(3) and SiO(2)-Bi(OTf)(3) are found to effectively catalyze the Ferrier rearrangement of tri-O-acetyl glycals with different alcohols providing an effective route to 2,3-unsaturated O-glycosides with good anomeric selectivity and good to excellent yields after short reaction times.
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| Publié dans: | Molecules |
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| Auteurs principaux: | , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
MDPI
2005
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6147713/ https://ncbi.nlm.nih.gov/pubmed/18007357 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/10080884 |
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