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Bi(OTf)(3) and SiO(2)-Bi(OTf)(3) as Effective Catalysts for the Ferrier Rearrangement#

Bi(OTf)(3) and SiO(2)-Bi(OTf)(3) are found to effectively catalyze the Ferrier rearrangement of tri-O-acetyl glycals with different alcohols providing an effective route to 2,3-unsaturated O-glycosides with good anomeric selectivity and  good to excellent yields after short reaction times.

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Podrobná bibliografie
Vydáno v:Molecules
Hlavní autoři: Babu, J. Lokesh, Khare, Anakshi, Vankar, Yashwant D.
Médium: Artigo
Jazyk:Inglês
Vydáno: MDPI 2005
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6147713/
https://ncbi.nlm.nih.gov/pubmed/18007357
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/10080884
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