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Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates†

The trichloromethylsulfonyl-, dichloromethylsulfonyl-, chlorosulfonyl-, and fluorosulfonyl esters of a neopentyl-type alcohol have been prepared via sulfonylation or sulfinylation followed by oxidation. The preparative usefulness and potential of the transformations are discussed.

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Pubblicato in:Molecules
Autori principali: Netscher, Thomas, Bohrer, Patrick
Natura: Artigo
Lingua:Inglês
Pubblicazione: MDPI 2002
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6146488/
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/70800601
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