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Synthesis of Cyclic β-Silylalkenyl Triflates via an Alkenyl Cation Intermediate

Trimethylsilylalkyne derivatives are transformed into cyclic β-silylalkenyl triflates through cationic cyclization and subsequent trapping of the alkenyl cation by a triflate anion. β-Silylcyclohexenyl triflates and 3-trimethylsilyl-1,4-dihydronaphth-2-yl triflates are generated efficiently using th...

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Bibliografske podrobnosti
izdano v:Org Lett
Main Authors: Lee, Craig J., Swain, Manisha, Kwon, Ohyun
Format: Artigo
Jezik:Inglês
Izdano: 2018
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC6133754/
https://ncbi.nlm.nih.gov/pubmed/30118234
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.8b02398
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