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Tyrosine-coordinated P-cluster in G. diazotrophicus nitrogenase: Evidence for the importance of O-based ligands in conformationally gated electron transfer
The P-cluster is a unique iron-sulfur center that likely functions as a dynamic electron (e(−)) relay site between the Fe-protein and the catalytic FeMo-cofactor in nitrogenase. The P-cluster has been shown to undergo large conformational changes upon 2-e(−) oxidation which entail the coordination o...
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| Udgivet i: | J Am Chem Soc |
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| Main Authors: | , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2016
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6129449/ https://ncbi.nlm.nih.gov/pubmed/27487256 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b06783 |
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