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Divergent ring-opening coupling between cyclopropanols and alkynes under cobalt catalysis

Cobalt–diphosphine catalysts promote ring-opening coupling reactions between cyclopropanols and unactivated internal alkynes, affording either β-alkenyl ketones or multisubstituted cyclopentenol derivatives in good yields with good to excellent regioselectivities. The chemoselectivity between these...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Yang, Junfeng, Shen, Yixiao, Lim, Yang Jie, Yoshikai, Naohiko
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6124909/
https://ncbi.nlm.nih.gov/pubmed/30210767
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc02074d
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