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Dimethylcethrene: A Chiroptical Diradicaloid Photoswitch

[Image: see text] We describe the synthesis and properties of 13,14-dimethylcethrene, a prototype of a chiral diradicaloid photochemical switch that can be transformed reversibly via conrotatory electrocyclization to its more stable closed form by light (630 nm) or heat and back to its open form by...

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Detalles Bibliográficos
Publicado en:J Am Chem Soc
Main Authors: Ravat, Prince, Šolomek, Tomáš, Häussinger, Daniel, Blacque, Olivier, Juríček, Michal
Formato: Artigo
Idioma:Inglês
Publicado: American Chemical Society 2018
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC6120736/
https://ncbi.nlm.nih.gov/pubmed/30067898
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b05465
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