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Dimethylcethrene: A Chiroptical Diradicaloid Photoswitch
[Image: see text] We describe the synthesis and properties of 13,14-dimethylcethrene, a prototype of a chiral diradicaloid photochemical switch that can be transformed reversibly via conrotatory electrocyclization to its more stable closed form by light (630 nm) or heat and back to its open form by...
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| Udgivet i: | J Am Chem Soc |
|---|---|
| Main Authors: | , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
American Chemical
Society
2018
|
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6120736/ https://ncbi.nlm.nih.gov/pubmed/30067898 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b05465 |
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