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Rhodium catalyzed cascade cyclization featuring B–H and C–H activation: one-step construction of carborane-fused N-polyheterocycles

A one-pot strategy for efficient and facile synthesis of C,B-substituted carborane-fused N-polyheterocycles is reported. A rhodium catalyzed cascade cyclization of carboranyl N-arylimines with vinyl ketones enables the effective construction of three new B–C and C–C bonds in one reaction. Both carbo...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Lyu, Hairong, Quan, Yangjian, Xie, Zuowei
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6115682/
https://ncbi.nlm.nih.gov/pubmed/30310567
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc01568f
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