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A Stereodivergent Rhodium(III)-Catalyzed Cis-Cyclopropanation Enabled by Multivariate Optimization

The design of stereodivergent transformations is of great interest to the synthetic community as it allows to funnel a given reaction pathway toward one stereochemical outcome or another by only minor adjustments of the reaction setup. Herein, we present a physical organic approach to invert the sen...

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Bibliographic Details
Published in:J Am Chem Soc
Main Authors: Piou, Tiffany, Romanov-Michailidis, Fedor, Ashley, Melissa A., Romanova-Michaelides, Maria, Rovis, Tomislav
Format: Artigo
Language:Inglês
Published: 2018
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Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC6112604/
https://ncbi.nlm.nih.gov/pubmed/30033723
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b04243
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