C−H Borylation/Cross‐Coupling Forms Twisted Donor–Acceptor Compounds Exhibiting Donor‐Dependent Delayed Emission

Benzothiadiazole (BT) directed C−H borylation using BCl(3), followed by B−Cl hydrolysis and Suzuki–Miyaura cross‐coupling enables facile access to twisted donor–acceptor compounds. A subsequent second C−H borylation step provides, on arylation of boron, access to borylated highly twisted D−A compoun...

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發表在:Chemistry
Main Authors: Crossley, Daniel L., Kulapichitr, Pakapol, Radcliffe, James E., Dunsford, Jay J., Vitorica‐Yrezabal, Inigo, Kahan, Rachel J., Woodward, Adam W., Turner, Michael L., McDouall, Joseph J. W., Ingleson, Michael J.
格式: Artigo
語言:Inglês
出版: John Wiley and Sons Inc. 2018
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC6099339/
https://ncbi.nlm.nih.gov/pubmed/29781115
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201801799
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