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Backbone Dehydrogenation in Pyrrole-Based Pincer Ligands

Treatment of both [CoCl((tBu)PNP)] and [NiCl((tBu)PNP)] ((tBu)PNP = anion of 2,5-bis((di-tert-butylphosphino)methyl)pyrrole) with one equivalent of benzoquinone affords the corresponding chloride complexes containing a dehydrogenated PNP ligand, (tBu)dPNP ((tBu)dPNP = anion of 2,5-bis((di-tert-butyl...

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Publicat a:Inorg Chem
Autors principals: Mahesh Krishnan, V., Davis, Ian, Baker, Tessa M., Curran, Daniel J., Arman, Hadi D., Neidig, Michael L., Liu, Aimin, Tonzetich, Zachary J.
Format: Artigo
Idioma:Inglês
Publicat: 2018
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6090532/
https://ncbi.nlm.nih.gov/pubmed/30040391
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.8b01643
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