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Synthesis, Characterization, and Catalytic Activity of Ni(II) Alkyl Complexes Supported by Pyrrole-Diphosphine Ligands
The organometallic Ni(II) chemistry of the pyrrole-based pincer ligands, (P(2) (R)Pyr)(−) (P(2) (R)Pyr = 2,5-(R(2)PCH(2))(2)C(4)H(2)N, R = Ph or Cy) is reported. Reactions of Grignard reagents with [NiCl(P(2)(R) Pyr)] afford a variety of alkyl and aryl complexes (methyl, ethyl, benzyl, phenyl, and a...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3931010/ https://ncbi.nlm.nih.gov/pubmed/24567662 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om400630q |
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